Tsymbal S.M., Shumlyanskyy L.V., Tsymbal Yu.S.
M.P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation of the National Academy of Science of Ukraine
Language: Ukrainian
Geochemistry and ore formation 2018, 39: 66-76
https://doi.org/10.15407/gof.2018.39.066
Age and crystallization temperature, as well as chemical composition of rutile from diamondiferous conglomerates and sandstones of the Palaeoproterozoic Bilokorovychi basin, are defined. Age of these terrigenous sediments is defined between 1800 and 1960 Ma. According to their chemical composition, rutiles belong to two groups, metapelitic and metamafitic, whereas according to the crystallization temperatures the 550–610 and 660–760 ºC groups can be defined. Rutiles derived from eclogitised mafic rocks belong exclusively to the first group whereas rutiles derived from metamorphosed ultramafic rocks fall predominantly into the second group; rutiles derived from metapelites fall into both groups. Ages of the studied rutiles vary from the Late Archaean (2650 Ma) to the Palaeoproterozoic (c. 1800 Ma); most of them are Palaeoproterozoic in age (2250–2060 Ma).
Keywords: rutile, geochronology, terrigenous sedimentary rocks, Palaeoproterozoic, the Ukrainian Shield.
References
1. Bespalko, N.A. (1986). Geological setting of the Bilokorovychi structure. Geol. journ. 46. No. 3, pp. 25-33. [in Russian].
2. Bukovich, I.P. (1986). Stratigraphy of the Vilchany, Ovruch and Bilokorovychi basins. Geol. journ. 46. No. 2, pp. 102–110 [in Russian].
3. Vyshnevsky, O.A., Kvasnytsya, V.M., Kvasnytsya, I.V., Shumlyanskyy, L.V., Gurnenko, I.V. (2015). Zircon from the Bilokorovychi Proterozoic sandstones (crystallomorphology, anatomy, chemical composition, mineral inclusions, genesis). Zapysky UMT. 12, pp. 88-102 [in Ukrainian].
4. Geyko, Yu.V., Gurskyi, D.S., Lykov, L.I., Metalidi, V.S., Pavlyuk, V.N., Prikhodko, V.L., Tsymbal, S.N., Shimkiv, L.M. (2006). The prospects of the bedrock diamond potencial of Ukraine. Kyiv-Lviv. 200 p. [in Russian].
5. Kvasnytsya, V.M. (2015). Precambrian diamonds of the Volyn terraine. Zapysky UMT. 12, pp. 165-168. [in Ukrainian].
6. Kvasnytsya, V.M., Vyshnevsky, O.A., Stepanyuk, L.M., Zhuk, O.M. (2016). Zircon from the Bilokorovychi Proterozoic conglomerates (the Ukrainian Shield). Zapysky UMT. 13, pp. 26-31 [in Ukrainian].
7. Kvasnytsya, V.M., Pavlyuk, O.V., Vyshnevsky, O.A., Kvasnytsya, I.V., Vysotsky, B.L., Gurnenko, I.V. (2015). Native gold from the Bilokorovychi Proterozoic conglomerates of the Volyn gerion. Zapysky UMT. 12, pp. 103-116 [in Ukrainian].
8. Kvasnytsya, V.M., Pavlyuk, O.V., Kvasnytsya, I.V., Vysotsky, B.L., Gurnenko, I.V. (2014). Finding of native tungsten microcrystals in the Bilokorovychi Proterozoic conglomerates of the Volyn gerion. Dopov. Nac. Acad. nauk Ukr. No. 11, pp. 88-94 [in Ukrainian].
9. Kvasnytsya, V.M., Taran, M.M., Wirth, R., Wiedenbeck, M., Thomas, R., Ilchenko, K.O., Lupashko, T.M. (2005) New data on Ukrainian diamonds. Mineral. Journ. 27. No. 4, pp. 47-58 [in Ukrainian].
10. Komarov, A.N., Prytkov, F.Ya. (1981). Structural-geological conditions and mechanism of formation of the tectono-metasomatic zones of the Volyn block. Geol. Journ. 41. No. 3, pp. 113-122 [in Russian].
11. Komarov, A.N., Prytkov, F.Ya. (1978). Tectono-metasomatic zones as a new type of faults in the Volyn block. Geol. journ. 38. No. 5, pp. 59-70 [in Russian].
12. Matkovsky, O.I., Slyvko, E.M. (2015). Mineralogical peculiarities of conglomerates of the Bilokorovychi structure (northwestern part of the Ukrainian Shield). Zapysky UMT. 12, pp. 23-53 [in Ukrainian].
13. Metalidi, S.V., Zaritskiy, A.I., Tsymbal, S.N., Kvasnytsa, V.N., Yazvinskiy, V.I. (1982). The first finding of diamond in conglomerates of the upper Proterozoic in the East European platform. Mineral. Journ. 4. No. 3, pp. 20-29 [in Russian].
14. Sobolev, N.V., Lavrentev, Yu.G., Usova, L.V. (1972). On trace elements in rutiles from eclogites. Geologiya i geofizika. No. 1, pp. 108-112 [in Russian].
15. Udovkina, N.G. (1985). Eclogites of the USSR. Moscow: Nauka, 285 p. [in Russian].
16. Fenoshyna, U.I., Slivko, E.M. (1999). Diamonds and their mineral sattelites in conglomerates of the Bilokorovychi structure (north-western part of the Ukrainian Shield). Visnyk Lvivskogo Universytetu, Seriya geologichna. 14, pp. 86-93 [in Ukrainian].
17. Tsymbal, S.M. (2015). Mineral sattelites of diamond in conglomerates and sanstones of the Bilokorovychi Suite of the Lower Proterozoic of the northern part of the Ukrainian Shield. Zapysky UMT. 12, pp. 54-75 [in Ukrainian].
18. Tsymbal, S.M., Vyshnevsky, O.A., Vuiko, V.I. (1984). The first finding of pyrope and chromediopside in coarse-grained terrigenous rocks of the Bilokorovychi Suite in the northern part of the Ukrainian Shield. Dopov. AN URSR, Seriya B. No. 8, pp. 26-31 [in Ukrainian].
19. Tsymbal, Yu.S. (2015). Detrital crustal-type orthopyroxenes and amphiboles from terrigenous sediments of the Bilokorovychi Suite, northern part of the Ukrainian Shield. Zapysky UMT. 12, pp. 76-87 [in Ukrainian].
20. Shumlyanskyy, L., Mazur, M. (2010). Age and composition of jotunites of the Bilokorovychi dyke swarm. Geolog Ukrainy. No. 1-2, pp. 70-78 [in Ukrainian].
21. Shumlyanskyy, L.V. (2011). The stratigraphic setting and provenance of the Bilokorovychi and Ovruch basins deposits (north-western part of the Ukrainian Shield). Geochemistry and Ore Formation. 29, pp. 44-53 [in Ukrainian].
22. Shumlyanskyy, L.V., Petrenko, O.V., Omelchenko, A.M. (2015). The Bilokorovychi basin at the north-western part of the Ukrainian Shield: geological setting, composition, age, genesis. Zapysky UMT. 12, pp. 8-22 [in Ukrainian].
23. Shumlyanskyy, L.V., Stepanyuk, L.M., Claesson, S., Rudenko, K.V., Bekker, A.Yu. (2018). U-Pb zircon and monazite geochronology of granitoids of the Zhytomyr and Sheremetiv complexes, the North-Western region of the Ukrainian Shield. Mineral. Journ. 40. No. 2, pp. 63-85[in Ukrainian].
https://doi.org/10.15407/mineraljournal.40.02.063
24. Amelin, Yu.V., Heaman, L.M., Verkhogliad, V.M., Skobelev, V.M. (1994). Geochronological constraints on the emplacement history of an anorthosite-rapakivi granite suite: U-Pb zircon and baddeleyite study of the Korosten complex, Ukraine. Contrib. Mineral. Petrol. 116, pp. 411-419.
https://doi.org/10.1007/BF00310908
25. Kvasnytsya, V., Shumlyanskyy, L. (2018). Native gold and diamonds from the Palaeoproterozoic terrigenous rocks of the Bilokorovychi basin, North-Western part of the Ukrainian shield. Mineral. Journ. 40. No. 3, pp. 23-38.
https://doi.org/10.15407/mineraljournal.40.03.023
26. Shumlyanskyy, L., Bekker, A., Claesson, S. (2015). U-Pb zircon geochronology of rocks of the Teteriv series, Northwestern region of the Ukrainian shield. Aktualnye problem nauk o Zemle. Geologicheskie i geograficheskie issledovaniya transgranichnykh regionov. Brest, 21–25 September 2015, pp. 242-244.
27. Shumlyanskyy, L., Hawkesworth, C., Billström, K., Bogdanova, S., Mytrokhyn, O., Romer, R., Dhuime, B., Claesson, S., Ernst, R., Whitehouse, M., Bilan, O. (2017). The origin of the Palaeoproterozoic AMCG complexes in the Ukrainian Shield: new U-Pb ages and Hf isotopes in zircon. Precam. Res. 292. P. 216-239.
https://doi.org/10.1016/j.precamres.2017.02.009
28. Shumlyanskyy, L., Hawkesworth, C., Dhuime, B., Billström, K., Claesson, S., Storey, C. (2015). 207Pb/206Pb ages and Hf isotope composition of zircons from sedimentary rocks of the Ukrainian shield: crustal growth of the south-western part of East European craton from Archaean to Neoproterozoic. Precam. Res. 260. P. 39-54.
https://doi.org/10.1016/j.precamres.2015.01.007
29. Tomkins, H.S., Powell, R., Ellis, D.J. (2007). The pressure dependence of the zirconium-in-rutile thermometer. J. Metamorphic. Geol. 25. P. 703-713.
https://doi.org/10.1111/j.1525-1314.2007.00724.x
30. Triebold, S., von Eynatten, H., Luvizotto, G.L., Zack, T. (2007). Deducing source rock lithology from detrital rutile geochemistry: an example from the Erzgebirge, Germany. Chem. Geol. 244. P. 421-436.
https://doi.org/10.1016/j.chemgeo.2007.06.033
31. Zack, T., Kronz, A., Foley, S.F., Rivers, T. (2002). Trace element abundances in rutiles from eclogites and associated garnet mica schists. Chem. Geol. 184. P. 979-122.
https://doi.org/10.1016/S0009-2541(01)00357-6
32. Zack, T., Moraes, R., Kronz, A. (2004). Temperature dependence of Zr in rutile: empirical calibration of a rutile thermometer. Contrib. Mineral. Petrol. 148. P. 471-488.
https://doi.org/10.1007/s00410-004-0617-8
33. Zack T., von Eynatten, H., Kronz, A. (2004). Rutile geochemistry and its potential use in quantitative provenance studies. Sediment. Geol. 171. P. 37-58.
https://doi.org/10.1016/j.sedgeo.2004.05.009