Omelchenko A.N.¹, Tomurko L.L.²
1 – Taras Shevchenko National University of Kyiv
2 – M.P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation of the National Academy of Sciences of Ukraine
Language: Russian
Geochemistry and ore formation 2016, 37: 43-58
https://doi.org/10.15407/gof.2016.37.043
A summary review of published information as well as of new data on the geological-petrographical and petrochemical peculiarities of amphibolites from the Ukrainian shield (USh) was carried out. Entry. Precambrian аmphibolites are widely spread within the territory of Ukrainian shield in the metamorphic complexes of different composition, stratigraphic position and age. Brief geological essay. Аmphibolites make stratum-shaped, rarely lens-shaped and dike-shaped bodies, sills, sheets of infinite thickness (0,n – n ´ 100 m). Mineralogical and petrographical features. Typical paragenesis of amphibolites is Hb + Pl. Plagioclase, pyroxene-containing and garnet- containing amphibolites are distinguished among them by mineral composition. Plagioclase amphibolites predominate while pyroxene-containing ones are less presented. Garnet amphibolites are spread in the USh territory ingsignificantly although being described in many areas. Amphiboles in amphibolites belong to the calcium group. Their chemical composition corresponds to magnesian differences of pargasite-gastingsite and hornblende sequences. Pyroxenes are represented by relict grains. Plagioclase corresponds mostly with andesine. The composition of garnet is grossular-almandine. Garnets from amphibolites of most eroded Dniester-Bug and Azov megablocks have a high content of pyrope component (15-28%), which testifies to the high pressure while crystallization and is typical for areas of granulite metamorphism. Petrochemical features. By average composition USh amphibolites are close to each other as well as to the amphibolites of other world regions. Amphibolites under investigation belong to tholeiitic petrochemical series of normal alkalinity according to their composition. Both volcanic (tholeiitic basalts) and plutonic (gabbro) rocks were proved to be the protoliths for studied amphibolites.
Key words: amphibolite, Ukrainian shield, petrochemistry , amphibole, garnet, tholeiitic basalt.
References
1. Batievski, B.A., Lugovaya, I.P . (1978). Geological journal. [On the nature of the parental rock of amphibolites of central part of the Ukrainian shield according to the oxygen isotopic analysis]. 38, № 3. P . 94-100 [Russian].
2. Beus, A.A. (1981). [Geochemistry of the Lithosphere]. Moscow: Nedra. 295 p. [Russian].
3. Bukharev , V.P . (1992). [The evolution of Precambrian magmatism in the western part of the Ukrainian shield]. Kiev: Nauk. dumka. 152 p. [Russian].
4. Venidiktov , V.M. (1979). [Pridnestrovie Precambrian geology and some problems of geology of the Ukrainian shield]. Kiev: Nauk. dumka. 226 p. [Russian].
5. Gatsenko, V.O. (2014). [The garnet amphibolites of Golovanov seam zone of the Ukrainian shield]. Abstracts of the International scientific conference devoted by 90th anniversary of ac. N. P . Shcherbaka: Geochronology and Geodynamics of the Early Precambrian (3,6-1,6 billion years) Eurasian continent. Kiev, 16-17 septeber 2014. Кiev. P . 3435. [Ukrainian].
6. [Geological and geophysical model Nemirov-Kocharovskaya seam zone of the Ukrainian shield] (2009). A.V. Antsiferov , E.M. Sheremet, K.E. Esipchuk, V.A. Antsiferov , P .I. Pigulevski, S.N. Kulik, T .K. Burakhovich, S.G. Krivdik, V.N. Zagnit ko, Yu.I. Nikolaev , I. Yu. Nikolaev , L.D. Setaya, V.V. Zyultsle, l.P . Nikitash. Donetsk. 253 p. [Russian].
7. [Geochemistry of oceanic and continental magmatism]. (1980). Moscow: Nedra. 247 p. [Russian].
8. Gonshakova, V.I., Osipov B.V., Chizhova I.A. (1982). Sovetskaya geologiya. [About petrochemical difference between basalt and dolerite alkalinity]. № 5. P . 77-86. [Russian].
9. Egorov , Yu.P . (1985). Geological journal. [The chemical compositions of rocks, regional clarkes and geochemical backgrounds of the chemical elements of the Ukrainian shield]. 45, № 2. P . 83-96. [Russian].
10. Kanevski, A.Ya.(1988). Geological journal. [The distribution of titanium and iron in the mafic and metamafitah Middle Bug]. № 2. P . 97-101. [Russian].
11. [Catalogue isotopic dates of the Ukrainian shield]. (1978).Shcherbak, N.P ., Zlobenko, V.G., Zhukov , G.V., Kotlovskaya, F .I., Polevaya, N.I., Komlev , L.V., Kovalenko, N.K., Nosok, G.M., Poshtarenko, V.M. Kiev: Naukova dumka. 211 p. [Russian].
12. Koli, V.D. (1982). The Problems of paleovulkanologic reconstructions of Access and mapping in connection with volcanogenic ore formation. Part 1. [Cummingtonite-hornblende amphibolite formation of Teterivskaya series]. Kiev: Nauk. dumka. P . 51-52. [Russian].
13. Koli, V.D. (1983). Geological journal. [Formations and stratigraphy of lower dokembrian formations Volyn geoblock (Ukrainian shield)]. № 6. P . 21-33. [Russian].
14. Kravchenko G.L. (2007). Geological journal. [The Nature of Manguska magnetic anomaly of South-East Priazov’ya]. № 4. P . 41-51. [Ukrainian].
15. Kravchenko, G.L., Krivdik, S.G., Boyko, L.V. (2007). Geochemistry and ore formation. [New data on the composition of the earliest rocks Novopavlovsk complex Orekhovo-Pavlograd zone of the Ukrainian shield]. 25. P . 15-37. [Russian].
16. Kutolin, V.A. (1972). [Problems of petrochemistry and petrology of basalts]. Novosibirsk: Nauka. 208 p. [Russian].
17. Lazko, E.M., Kirilyuk, V.P ., Lisak, A.M. (1984). Geological journal. [The geological formations and problems of stratigraphy Lower Precambrian Ukrainian Shield]. 44,№2. P . 103-112. [Russian].
18. Lesnaya, I.M. (1975).Geological journal.[Accessory minerals of amphibolites headwaters Ros].35, № 6. P . 135-138. [Russian].
19. Lutts, B.G. (1980). [Geochemistry of oceanic and continental magmatism]). Moscow: Nedra. 247 p. [Russian].
20. Lisak, A.M., Sivoronov , A.A. (1976). Geological journal.[Petrographical and geochemical features of gneiss-amphibolite formations basin Bazavluk (Ukrainian shield)]. 36,№6. P . 55-67. [Russian].
21. [Igneous rocks. Classification. Nomenclature. Petrography]. Part 1. (1983). V.D. Andreena, V.A. Baskina, V.A. Bogatikov , M.B. Borodaevskaya, V.I. Gonshakova, L.S. Egorov , S.V. Efremova, V.I. Kovalenko, E.E. Lazko, B.A. Markovski, V.L.Ma sai tis, N.P . Mihailov , V.V. Nasedkin, P .N. Sobolev , T .L.Filippova, T .I. Frolova, R.M. Yashina.Moscow:Nauka. 367 p. [Russian].
22. [Igneous rocks. Basic rocks]. (1985). V.D. Andreena, V.A. Bogatikov , A.M. Borsuk, V.I. Gonshakova, Yu.I. Dmitriev , I.S. Krasivskaya, E.E. Lazko, A.K. Simon, M.K. Suhanov , A.A. Frih-Har, A.A. Tsvetkov , S.V. Chesnokov , E.V. Sharikov . Moscow: Nauka. 438 p. [Russian].
23. [Igneous rocks. Evolution of magmatism in the Earth’s history]. (1987). V.D. Andreena, V.A. Baskina, V.A. Bogatikov , M.B. Boroda ev skaya, V.I. Gonshakova, L.S. Egorov , S.V. Efremova, V.I. Kovalenko, E.E. Lazko, B.A. Markovski, V.L. Ma sai tis, N.P . Mihailov , V.V. Nasedkin, P .N. Sobolev , T .L. Filippova, T .I. Frolova, R.M. Yashina. Moscow: Nauka. 438 p.
[Russian].
24. Medvedeva, I.E. (1973). [Geochemistry. Mineralogy. Petrography]. 7.[Amphibolites: current data on the material composition and the genesis]. Moscow . P .100-143.
25. [Nomenclature of amphiboles: report of the subcommittee on amphiboles of the Commission on New Minerals and mine ral names of the International Mineralogical Association (CNMMN IMA)]. (1997). Zapiski Vsesoyuznogo Mineralogiche skogo obshchestva. № 6. P . 82-102.
26. Orsa, V.I. (1988). [Formaition of Granites in the Precambrian in Srednepridneprovsky granite-greenstone region]. Kiev: Nauk. dumka. 202 p. [Russian].
27. [Petrografіc Code of Ukraine] (1999). R.Ya. Belevtsev , V.A. Velikanov , Yu.L. Gasanov , K.E. Esipchuk, S.G. Krivdik, V.G. Molyavko, V.M. Skobelev , I.B. Shcherbakov , B.G. Yakovlev . Kiev . 81 p.
28. [Petrographic Code of Russia. Igneous, metamorphic, metasomatic, impact of education]. (2009). V.V. Zhdanov , A.E. Kostin, E.A.Kukharenko, E.A. Landa, I.I.Lukyanova,V.V. Masaitis, Z.D. Moskalenko, Yu.D. Pushkarev , L.N. Shar pe nok. Sankt-Peterburg. 202 p. [Russian].
29. [Petrographic dictionary]. (1981). R.P . Petrov , A.M. Demin, A.I. Ezhova, V.I. Gonshakova, K.G. Stafeev , V.D. Andreena, S.V. Efremova, E.E. Lazko, A.M. Barsuk. Moscow: Nedra. 496 p. [Russian].
30. [Rock-forming grenades Ukrainian shield]. (1980). I.S. Usenko, R.Ya. Belevtsev , T .G. Shcherbakova, B.G. Yakovlev , G.L. Kravchenko G.L., V.I. Orsa, K.E. Esipchuk, E.N.Golub, E.A. Nikulina, V.V. Slipchenko, V.S. Dudko, S.I. Te reshchen ko, T .P . Homyak, V.M. Venidiktov . Kiev: Naukova dumka. 175 p. [Russian].
31. Ryabokon, V.V., Shcherbakov , I.B. (1977). [Sobits of Ukrainian shield and their genesis]. Preprint IGFM AN of Ukraine. Kiev . 54 p.
32. Sivoronov , A.A., Maluk, B.I., Berzenin, B.Z., Bobrov , A.B., Voronova, S.G. (1981). Geological journal. [ Metamorphosed volcanic formations of earlyprecambrian greenstone belts of the Ukrainian shield. Article 2. Petrochemical and genesis.]. 41, № 6. P . 19-28. [Russian].
33. Sidorenko, A.V., Tenyakov , V.A., Rozen, O.M., Zhuk-Pocheketov , K.A., Gorbachov , O.V. (1972). [Para- and ortoamfibolites of Precambrian. State of the problem and the experience of the analysis on the example of amphibolites of the Kola Peninsula.]. Moscow: Nauka. 211 p. [Russian].
34. Slipchenko V.V. (1978). Geological journal.[On the genesis of metabasites of the Middle Bug (by petrochemical data)]. №1. P . 113-121. [Russian].
35. Usenko, I.S. (1953). [Archean metabasites and ultrabasites Ukrainian crystalline massif]. Kiev . – 100 p.
36. Usenko, I.S. (1948). [Metabasites of Dnieper (petrographic character)]. Kiev . 100 p.
37. Usenko, I.S. (1958). [Basic and ultrabasic rocks of the basin of the Southern Bug]. 143 p.
38. Usenko, I.S. (1960). [Basic and ultrabasic rocks of the Western Azov Sea]. Kiev . 179 p.
39. Usenko, I.S. , Shcgerbakov , I.B., Zayats, A.P . (1972). [Biotites of Precambrian]. Kiev: Naukova dumka. 150 p. [Russian].
40. Usenko, I.S., Shcgerbako, I.B., Siroshtan, R.I., Belevtsev , R.Ya., Atingof, I.M., Shcgerbakova, T .G., Polovko, N.I., Krav chen ko, G.L., Yakovlev , B.G., Orsa, V.I., Venidiktov , V.M., Zultsle, V.V., Hvorova, G.P ., Bilinsraya, Yz.P ., Piyar, U.K., Go lub, E.N., Ro kachuk, T .A., Esipchuk, K.E., Yaroshchuk, M.A., Nikulina, A.A., Kirillov , St.G., Skenzak, S.I., Stepchen ko, S.B., Sharkin, O.P ., Glevasski, E.B., Mineeva, V.N., Batievski, B.A. (1982). [The metamorphism of the Ukrainian shield]. Kiev: Nauk. dumka. 306 p. [Russian].
41. Fomin, A.B. [Geochemistry of ultramafic rocks of the Ukrainian shield]. Kiev: Naukova dumka. 231 p. [Russian].
42. Shcherbak, N.P ., Artemenko, G.V., Lesnaya, I.M., Ponomarenko, A.N. (2005). [Geochronology Early Precambrian of the Ukrainian Shield. Arhean]. Kiev: Nauk. dumka. 244 p. [Russian].
43. Shcherbak, N.P ., Artemenko, G.V., Lesnaya, I.M., Ponomarenko, A.N., Shumlianski, L.V. (2008).[Geochronology Early Precambrian of the Ukrainian Shield. Proterozoic]. Kiev: Nauk. dumka. 239 p. [Russian].
44. Shcgerbakov , I.B. (1975). [Petrography of the Precambrian rocks of the central part of the Ukrainian shield]. Kiev: Nauk. dumka. 279 p. [Russian].
45. Shcgerbakov , I.B. (2005). [Petrology of the Ukrainian shield]. Lvov: Izdatelstvo ZUKTs. 364 p.
46. Yakovlev , B.G.(2976). Mineralogical collection. [Isomorphism and geochemical conditions of formation of garnets from ferrous and basic rocks of the Middle Bug]. № 30. 2. P . 21-30. [Russian].
47. Yaroshchuk M.A. (1983). [Iron ore formation Belotserkovsko-Odessa metallogenic zone]. Kiev: Nauk. dumka. 224 p. [Russian].
48. Miyashiro, A. (1974). Amer. J. Sci. [Volcanic rock in Island Arcs and active continental marins]. 274. P . 321-343.
49. Robertson, S. (1999). [BGS Rock Classification Scheme. Vol.2. Classification of metamorphic rocks]. British Geological Survey Research Report, RR 99-02. British Geological Survey, Keywoth, Nottinghem NG 12 5GG, UK. 24 p.