{"id":2441,"date":"2025-12-16T12:31:37","date_gmt":"2025-12-16T10:31:37","guid":{"rendered":"https:\/\/www.g-o-f.org.ua\/?page_id=2441"},"modified":"2025-12-18T13:39:16","modified_gmt":"2025-12-18T11:39:16","slug":"gof-2025-46-072","status":"publish","type":"page","link":"https:\/\/www.g-o-f.org.ua\/gb\/archive\/2025-46\/gof-2025-46-072\/","title":{"rendered":"FEATURES OF SILVER ACCUMULATION IN SOILS CONTAMINATED WITH SEWAGE SLUDGE (KYIV REGION, UKRAINE)"},"content":{"rendered":"

V<\/strong>.R.<\/strong> \u00a0Klos<\/strong>1,2<\/strong><\/sup>, https:\/\/orcid.org\/0009-0009-2965-0916<\/a>
\nN.O. \u00a0Kryuchenko<\/strong>2<\/strong><\/sup>, nataliya.kryuchenko@gmail.com, https:\/\/orcid.org\/0000-0001-8774-9089<\/a>
\nM.A. \u00a0Smyrnyi<\/strong>2<\/strong><\/sup>, https:\/\/orcid.org\/0009-0000-1274-6596<\/a><\/p>\n

1 State Enterprise \u201cUkrainian Geological Company\u201d, 02088, Geofizykiv Str., 10, Kyiv, Ukraine;
\n2 M.P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation of the National Academy of Sciences of Ukraine 34, Acad. Palladina Ave., Kyiv, Ukraine, 03142<\/p>\n

https:\/\/doi.org\/10.15407\/gof.2025.46.072<\/a><\/p>\n

The content of silver (gross and mobile forms) and organic matter in agricultural and pasture soils contaminated with sewage sludge from the Bortnytsia aeration station and conditionally \u201cclean\u201d soils of the Kyiv region was determined. Gross Ag concentrations were determined by approximate quantitative spectral analysis, mobile forms by atomic absorption, and organic matter content by volumetric chemical analysis.
\nThe background content of gross (0.14 mg\/kg) and mobile forms (0.000125 mg\/kg) of silver in the soils of the region was established. An inverse correlation (R2\u00a00.8) was found between the content of gross and mobile forms in the soils of contaminated agricultural and pasture lands, and a direct linear correlation (R2 0.8) in the soils of conditionally \u201cclean\u201d areas. It was found that silts have the highest gross silver content \u2014 6.7 mg\/kg and the highest organic matter content \u2014 20.6%, while soils of contaminated agricultural and pasture lands have approximately the same silver content (4\u20145 mg\/kg) and organic matter \u2014 4.2\u20144.4%; conditionally \u201cclean\u201d areas are characterized by the lowest silver content (0.11\u20140.18 mg\/kg) and the lowest organic matter content (1.3\u20142.1%).
\nIt has been established that the highest percentage of mobile silver forms is observed in the soils of conditionally \u201cclean\u201d pasture lands \u2014 0.18%, while the lowest percentage is characteristic of silt fields \u2014 0.003%, which is due to the fact that humic acids bind most silver complexes well. It was found that in contaminated agricultural soils, the content of mobile forms of silver is 4 times higher (0.00207 mg\/kg) than in soils on pasture lands, easily soluble (mobile) forms of silver are most accessible to plants.<\/p>\n

Keywords:<\/em><\/strong> silver (total content and mobile forms), organic matter, contaminated soils, conditionally \u201cclean\u201d soils, sewage sludge fields.<\/em><\/p>\n

Download<\/strong> (PD<\/strong>F)<\/strong><\/a><\/p>\n

Refer<\/strong>ence<\/strong><\/p>\n

Klos, V.R., Zhovynskyi, Ya., Kryuchenko, N.O., Prykhodko, M.V. (2017). Ecological and geochemical assessment of soils of the Kyiv region contaminated with sewage sludge. Geochemistry and Ore Formation. <\/em>38, pp. 95-100. https:\/\/nbuv.gov.ua\/UJRN\/geoch_2017_38_9<\/a> [in Ukranian].<\/p>\n

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Haddix, L., Gregorich, E.G., Helgason, B.L., Janzen, H., Ellert, B.H., Cotrufo, M.F. (2020). Climate, carbon content, and soil texture control the independent formation and persistence of particulate and mineral-associated organic matter in soil. Geoderma. <\/em>363<\/strong>. Art. No. 114160. https:\/\/doi.org\/10.1016\/j.geoderma.2019.114160.<\/p>\n","protected":false},"excerpt":{"rendered":"

V.R. \u00a0Klos1,2, https:\/\/orcid.org\/0009-0009-2965-0916 N.O. \u00a0Kryuchenko2, nataliya.kryuchenko@gmail.com, https:\/\/orcid.org\/0000-0001-8774-9089 M.A. \u00a0Smyrnyi2, https:\/\/orcid.org\/0009-0000-1274-6596 1 State Enterprise \u201cUkrainian Geological Company\u201d, 02088, Geofizykiv Str., 10, Kyiv, Ukraine; 2 M.P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation of the National Academy of Sciences of Ukraine 34, Acad. Palladina Ave., Kyiv, Ukraine, 03142 https:\/\/doi.org\/10.15407\/gof.2025.46.072 The content of silver (gross and mobile … Continue reading “FEATURES OF SILVER ACCUMULATION IN SOILS CONTAMINATED WITH SEWAGE SLUDGE (KYIV REGION, UKRAINE)”<\/span><\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"parent":2361,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-2441","page","type-page","status-publish","hentry"],"translation":{"provider":"WPGlobus","version":"3.0.0","language":"gb","enabled_languages":["uk","gb"],"languages":{"uk":{"title":true,"content":true,"excerpt":false},"gb":{"title":true,"content":true,"excerpt":false}}},"jetpack_sharing_enabled":true,"jetpack_shortlink":"https:\/\/wp.me\/P9ghyZ-Dn","jetpack_likes_enabled":true,"jetpack-related-posts":[{"id":2084,"url":"https:\/\/www.g-o-f.org.ua\/gb\/archive\/2023-44\/1-1\/","url_meta":{"origin":2441,"position":0},"title":"AGE OF QUARTZ SYENITES OF THE NIZYANKA STRUCTURE OF THE WEST AZOV REGION","author":"admin","date":"17\/12\/2023","format":false,"excerpt":"{:uk}{:uk}{:uk}\u0413.\u0412. \u0410\u0440\u0442\u0435\u043c\u0435\u043d\u043a\u043e 1 E-mail: regulgeo@gmail.com; https:\/\/orcid.org\/0000-0002-4528-6853 \u0411.\u0412. \u0411\u043e\u0440\u043e\u0434\u0438\u043d\u044f 2 E-mail: boris.priazov@gmail.com \u041b.\u0421. \u0414\u043e\u0432\u0431\u0438\u0448 1 E-mail: dovbyshls@ukr.net; https:\/\/orcid.org\/0000-0003-4529-448X \u041e.\u0411. \u0412\u0438\u0441\u043e\u0446\u044c\u043a\u0438\u0439 1 E-mail: alek.vysotsky@gmail.com; https\/\/orcid.org\/0000-0002-3542-4685 \u0412.\u041e. \u0412\u0456\u043b\u044c\u043a\u043e\u0432\u0441\u044c\u043a\u0438\u0439 1 E-mail: V.vilkovskiy@gmail.com; https:\/\/orcid.org\/0009-0007-7117-8980 1\u0406\u043d\u0441\u0442\u0438\u0442\u0443\u0442 \u0433\u0435\u043e\u0445\u0456\u043c\u0456\u0457, \u043c\u0456\u043d\u0435\u0440\u0430\u043b\u043e\u0433\u0456\u0457 \u0442\u0430 \u0440\u0443\u0434\u043e\u0443\u0442\u0432\u043e\u0440\u0435\u043d\u043d\u044f \u0456\u043c. \u041c.\u041f. \u0421\u0435\u043c\u0435\u043d\u0435\u043d\u043a\u0430 \u041d\u0410\u041d \u0423\u043a\u0440\u0430\u0457\u043d\u0438 03142, \u043f\u0440\u043e\u0441\u043f. \u0410\u043a\u0430\u0434. \u041f\u0430\u043b\u043b\u0430\u0434\u0456\u043d\u0430, 34, \u041a\u0438\u0457\u0432, \u0423\u043a\u0440\u0430\u0457\u043d\u0430 2 \u041a\u041f \u00ab\u041f\u0456\u0432\u0434\u0435\u043d\u0443\u043a\u0440\u0433\u0435\u043e\u043b\u043e\u0433\u0456\u044f\u00bb 49000,\u2026","rel":"","context":"Similar post","block_context":{"text":"Similar post","link":""},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":2385,"url":"https:\/\/www.g-o-f.org.ua\/gb\/archive\/2025-46\/gof-2025-46-013\/","url_meta":{"origin":2441,"position":1},"title":"COMPARATIVE ANALYSIS OF ORE CONTENT IN THE MEZHYRICHNE ILMENITE DEPOSIT AREAS","author":"admin","date":"16\/12\/2025","format":false,"excerpt":"{:uk}\u041e.\u0410. \u0413\u0430\u043d\u0436\u04301, oag2909@gmail.com, https:\/\/orcid.org\/0000-0001-8510-5618 \u0404.\u0421. \u041b\u0443\u043d\u044c\u043e\u04322, lunev_00@ukr.net, https:\/\/orcid.org\/0000-0002-9999-8565 \u041a.\u041c. \u0421\u0442\u0430\u0440\u043e\u0434\u0443\u0431\u0435\u0446\u044c1, starodubets.kirill@ukr.net, https:\/\/orcid.org\/0000-0002-0887-1543 \u0406.\u041c. \u041b\u0443\u043d\u044c\u043e\u0432\u0430 2, gerasimetsirina@gmail.com, https:\/\/orcid.org\/0000-0003-4670-0216 \u0410.\u0412. \u0427\u0443\u043c\u0430\u043a 3, chymak209@ukr.net, https:\/\/orcid.org\/0009-0000-9225-278X 1 \u0406\u043d\u0441\u0442\u0438\u0442\u0443\u0442 \u0433\u0435\u043e\u043b\u043e\u0433\u0456\u0447\u043d\u0438\u0445 \u043d\u0430\u0443\u043a \u041d\u0410\u041d \u0423\u043a\u0440\u0430\u0457\u043d\u0438 01054, \u0432\u0443\u043b. \u041e\u043b\u0435\u0441\u044f \u0413\u043e\u043d\u0447\u0430\u0440\u0430, 55 \u0411, \u041a\u0438\u0457\u0432, \u0423\u043a\u0440\u0430\u0457\u043d\u0430 2 \u0406\u043d\u0441\u0442\u0438\u0442\u0443\u0442 \u0433\u0435\u043e\u0445\u0456\u043c\u0456\u0457, \u043c\u0456\u043d\u0435\u0440\u0430\u043b\u043e\u0433\u0456\u0457 \u0442\u0430 \u0440\u0443\u0434\u043e\u0443\u0442\u0432\u043e\u0440\u0435\u043d\u043d\u044f \u0456\u043c. \u041c.\u041f. \u0421\u0435\u043c\u0435\u043d\u0435\u043d\u043a\u0430 \u041d\u0410\u041d \u0423\u043a\u0440\u0430\u0457\u043d\u0438 03142, \u043f\u0440\u043e\u0441\u043f. \u0410\u043a\u0430\u0434.\u2026","rel":"","context":"Similar post","block_context":{"text":"Similar post","link":""},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":2434,"url":"https:\/\/www.g-o-f.org.ua\/gb\/archive\/2025-46\/gof-2025-46-063\/","url_meta":{"origin":2441,"position":2},"title":"THE INFLUENCE OF ORGANIC MATTER ON THE GEOCHEMISTRY OF FLUORINE IN BROWN SOILS OF TRANSCARPATHIEN (SVIDOVETS MASSIF)","author":"admin","date":"16\/12\/2025","format":false,"excerpt":"{:uk}{:uk} \u041d.\u041e.\u00a0 \u00a0\u041a\u0440\u044e\u0447\u0435\u043d\u043a\u043e1,\u00a0 \u00a0nataliya.kryuchenko@gmail.com,\u00a0 \u00a0https:\/\/orcid.org\/0000-0001-8774-9089 \u0415.\u042f. \u00a0\u0416\u043e\u0432\u0438\u043d\u0441\u044c\u043a\u0438\u04391, \u00a0https:\/\/orcid.org\/0000-0003-1601-5998 \u041f.\u0421. \u00a0\u041f\u0430\u043f\u0430\u0440\u0438\u0433\u04302, \u00a0https:\/\/orcid.org\/0000-0002-4021-0809 \u041c.\u0412. \u041a\u0443\u0445\u0430\u04401, https:\/\/orcid.org\/0000-0003-3572-5194 \u041e.\u0410. \u0416\u0443\u043a1, https:\/\/orcid.org\/0000-0002-5264-0750 \u0422.\u0410. \u041f\u043e\u043f\u0435\u043d\u043a\u043e1, https:\/\/orcid.org\/0009-0001-7524-8065 1\u00a0 \u00a0\u0406\u043d\u0441\u0442\u0438\u0442\u0443\u0442 \u0433\u0435\u043e\u0445\u0456\u043c\u0456\u0457, \u043c\u0456\u043d\u0435\u0440\u0430\u043b\u043e\u0433\u0456\u0457 \u0442\u0430 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90600,\u2026","rel":"","context":"Similar post","block_context":{"text":"Similar post","link":""},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":2037,"url":"https:\/\/www.g-o-f.org.ua\/gb\/archive\/2022-43\/10-2\/","url_meta":{"origin":2441,"position":3},"title":"GEOCHEMISTRY OF MICRO ELEMENTS IN BROWN SOILS WITH MOSS COVER OF THE CARPATIAN BIOSPHERE RESERVE","author":"admin","date":"20\/12\/2022","format":false,"excerpt":"{:uk} \u041d.\u041e. \u041a\u0440\u044e\u0447\u0435\u043d\u043a\u043e1E-mail: nataliya.kryuchenko@gmail.com, https:\/\/orcid.org\/0000-0001-8774-9089\u0415.\u042f. \u0416\u043e\u0432\u0438\u043d\u0441\u044c\u043a\u0438\u04391E-mail: zhovinsky@ukr.net, https:\/\/orcid.org\/0000-0003-1601-5998\u041f.\u0421. \u041f\u0430\u043f\u0430\u0440\u0438\u0433\u04302E-mail: paparyga.ps@ukr.net, https:\/\/orcid.org\/0000-0002-4021-0809\u041e.\u0410. \u0416\u0443\u043a1E-mail: igmof.zhuk@gmail.com, https:\/\/orcid.org\/0000-0002-5264-0750\u041c.\u0412. \u041a\u0443\u0445\u0430\u04401E-mail: mvk3@ukr.net, https:\/\/orcid.org\/0000-0003-3572-5194\u041a.\u0415. \u0414\u043c\u0438\u0442\u0440\u0435\u043d\u043a\u043e1E-mail: zovin.kosta@gmail.com, https:\/\/orcid.org\/0000-0003-1001-3457\u0422.\u0410. \u041f\u043e\u043f\u0435\u043d\u043a\u043e1E-mail: tanya_simple@ukr.net1. \u0406\u043d\u0441\u0442\u0438\u0442\u0443\u0442 \u0433\u0435\u043e\u0445\u0456\u043c\u0456\u0457, \u043c\u0456\u043d\u0435\u0440\u0430\u043b\u043e\u0433\u0456\u0457 \u0442\u0430 \u0440\u0443\u0434\u043e\u0443\u0442\u0432\u043e\u0440\u0435\u043d\u043d\u044f \u0456\u043c\u0435\u043d\u0456 \u041c.\u041f. \u0421\u0435\u043c\u0435\u043d\u0435\u043d\u043a\u0430 \u041d\u0410\u041d \u0423\u043a\u0440\u0430\u0457\u043d\u043803142, \u043f\u0440\u043e\u0441\u043f. \u0430\u043a\u0430\u0434. \u041f\u0430\u043b\u043b\u0430\u0434\u0456\u043d\u0430, 34, \u041a\u0438\u0457\u0432, \u0423\u043a\u0440\u0430\u0457\u043d\u04302. \u041a\u0430\u0440\u043f\u0430\u0442\u0441\u044c\u043a\u0438\u0439 \u0431\u0456\u043e\u0441\u0444\u0435\u0440\u043d\u0438\u0439 \u0437\u0430\u043f\u043e\u0432\u0456\u0434\u043d\u0438\u043a \u041c\u0456\u043d\u0456\u0441\u0442\u0435\u0440\u0441\u0442\u0432\u0430 \u043e\u0445\u043e\u0440\u043e\u043d\u0438 \u043d\u0430\u0432\u043a\u043e\u043b\u0438\u0448\u043d\u044c\u043e\u0433\u043e \u043f\u0440\u0438\u0440\u043e\u0434\u043d\u043e\u0433\u043e \u0441\u0435\u0440\u0435\u0434\u043e\u0432\u0438\u0449\u0430 \u0423\u043a\u0440\u0430\u0457\u043d\u043890600, \u0432\u0443\u043b. \u041a\u0440\u0430\u0441\u043d\u0435 \u041f\u043b\u0435\u0441\u043e,\u2026","rel":"","context":"Similar post","block_context":{"text":"Similar post","link":""},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":1903,"url":"https:\/\/www.g-o-f.org.ua\/gb\/archive\/2021-42\/1-2\/","url_meta":{"origin":2441,"position":4},"title":"COMPLEX GEOCHEMICAL CHARACTERISTICS OF SOILS AND PLANTS IN NATURAL RESERVE ZONES OF UKRAINE","author":"admin","date":"15\/12\/2021","format":false,"excerpt":"{:uk} \u041d.\u041e. \u041a\u0440\u044e\u0447\u0435\u043d\u043a\u043e 1 https:\/\/orcid.org\/0000-0001-8774-9089 \u0415.\u042f. \u0416\u043e\u0432\u0438\u043d\u0441\u044c\u043a\u0438\u0439\u00a01 https:\/\/orcid.org\/0000-0003-1601-5998 \u041f.\u0421. \u041f\u0430\u043f\u0430\u0440\u0438\u0433\u0430 2 https:\/\/orcid.org\/0000-0002-4021-0809 \u041e.\u0410. \u0416\u0443\u043a\u00a01 https:\/\/orcid.org\/0000-0002-5264-0750 \u041c.\u0412. \u041a\u0443\u0445\u0430\u0440\u00a01 https:\/\/orcid.org\/0000-0003-3572-5194 \u041a.\u0415. \u0414\u043c\u0438\u0442\u0440\u0435\u043d\u043a\u043e\u00a01 https:\/\/orcid.org\/0000-0003-1001-3457 \u0422.\u0410. \u041f\u043e\u043f\u0435\u043d\u043a\u043e\u00a01 1. \u0406\u043d\u0441\u0442\u0438\u0442\u0443\u0442 \u0433\u0435\u043e\u0445\u0456\u043c\u0456\u0457, \u043c\u0456\u043d\u0435\u0440\u0430\u043b\u043e\u0433\u0456\u0457 \u0442\u0430 \u0440\u0443\u0434\u043e\u0443\u0442\u0432\u043e\u0440\u0435\u043d\u043d\u044f \u0456\u043c. \u041c.\u041f. \u0421\u0435\u043c\u0435\u043d\u0435\u043d\u043a\u0430 \u041d\u0410\u041d \u0423\u043a\u0440\u0430\u0457\u043d\u0438, 03142, \u043f\u0440\u043e\u0441\u043f. \u0430\u043a\u0430\u0434. \u041f\u0430\u043b\u043b\u0430\u0434\u0456\u043d\u0430, 34, \u041a\u0438\u0457\u0432, \u0423\u043a\u0440\u0430\u0457\u043d\u0430 2. \u041a\u0430\u0440\u043f\u0430\u0442\u0441\u044c\u043a\u0438\u0439 \u0431\u0456\u043e\u0441\u0444\u0435\u0440\u043d\u0438\u0439 \u0437\u0430\u043f\u043e\u0432\u0456\u0434\u043d\u0438\u043a \u041c\u0456\u043d\u0456\u0441\u0442\u0435\u0440\u0441\u0442\u0432\u0430 \u0437\u0430\u0445\u0438\u0441\u0442\u0443 \u0434\u043e\u0432\u043a\u0456\u043b\u043b\u044f \u0442\u0430 \u043f\u0440\u0438\u0440\u043e\u0434\u043d\u0438\u0445\u2026","rel":"","context":"Similar post","block_context":{"text":"Similar 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1 https:\/\/orcid.org\/0009-0001-7524-8065 1 \u0406\u043d\u0441\u0442\u0438\u0442\u0443\u0442 \u0433\u0435\u043e\u0445\u0456\u043c\u0456\u0457, \u043c\u0456\u043d\u0435\u0440\u0430\u043b\u043e\u0433\u0456\u0457 \u0442\u0430 \u0440\u0443\u0434\u043e\u0443\u0442\u0432\u043e\u0440\u0435\u043d\u043d\u044f \u0456\u043c\u0435\u043d\u0456 \u041c.\u041f. \u0421\u0435\u043c\u0435\u043d\u0435\u043d\u043a\u0430 \u041d\u0410\u041d \u0423\u043a\u0440\u0430\u0457\u043d\u0438 \u043f\u0440\u043e\u0441\u043f. \u0430\u043a\u0430\u0434. \u041f\u0430\u043b\u043b\u0430\u0434\u0456\u043d\u0430, 34, \u041a\u0438\u0457\u0432, \u0423\u043a\u0440\u0430\u0457\u043d\u0430, 03142 2 \u041a\u0430\u0440\u043f\u0430\u0442\u0441\u044c\u043a\u0438\u0439 \u0431\u0456\u043e\u0441\u0444\u0435\u0440\u043d\u0438\u0439 \u0437\u0430\u043f\u043e\u0432\u0456\u0434\u043d\u0438\u043a \u041c\u0456\u043d\u0434\u043e\u0432\u043a\u0456\u043b\u043b\u044f \u0423\u043a\u0440\u0430\u0457\u043d\u0438, \u0432\u0443\u043b.\u2026","rel":"","context":"Similar post","block_context":{"text":"Similar 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