{"id":701,"date":"2018-07-14T17:47:38","date_gmt":"2018-07-14T14:47:38","guid":{"rendered":"http:\/\/www.g-o-f.org.ua\/?page_id=701"},"modified":"2019-05-27T16:56:14","modified_gmt":"2019-05-27T13:56:14","slug":"%d0%b2%d0%be%d0%b4%d0%b0-%d0%b2-%d0%ba%d0%b2%d0%b0%d1%80%d1%86%d1%96-%d1%8f%d0%ba-%d1%96%d0%bd%d0%b4%d0%b8%d0%ba%d0%b0%d1%82%d0%be%d1%80-%d1%96%d0%bd%d1%82%d0%b5%d0%bd%d1%81%d0%b8%d0%b2%d0%bd%d0%be","status":"publish","type":"page","link":"http:\/\/www.g-o-f.org.ua\/gb\/archive\/2016-2\/%d0%b2%d0%b8%d0%bf%d1%83%d1%81%d0%ba-37\/%d0%b2%d0%be%d0%b4%d0%b0-%d0%b2-%d0%ba%d0%b2%d0%b0%d1%80%d1%86%d1%96-%d1%8f%d0%ba-%d1%96%d0%bd%d0%b4%d0%b8%d0%ba%d0%b0%d1%82%d0%be%d1%80-%d1%96%d0%bd%d1%82%d0%b5%d0%bd%d1%81%d0%b8%d0%b2%d0%bd%d0%be\/","title":{"rendered":"Water in quartz as the indicator of intensity of hydrothermal ore formation: gold ore deposits"},"content":{"rendered":"<p><strong><em>Kalinichenko <\/em><\/strong><strong><em>\u0415<\/em><\/strong><strong><em>.<\/em><\/strong><strong><em>\u0410<\/em><\/strong><strong><em>., Brik <\/em><\/strong><strong><em>\u0410<\/em><\/strong><strong><em>.B., Kalinichenko <\/em><\/strong><strong><em>\u0410<\/em><\/strong><strong><em>.<\/em><\/strong><strong><em>\u041c<\/em><\/strong><strong><em>., Yushin A.A.<\/em><\/strong><br \/>\nM.P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation of the National Academy of Sciences of Ukraine<\/p>\n<p>Language: Ukrainian<br \/>\nGeochemistry and ore formation 2016, 37: 65-73<\/p>\n<p><a href=\"https:\/\/doi.org\/10.15407\/gof.2016.37.065\">https:\/\/doi.org\/10.15407\/gof.2016.37.065<\/a><\/p>\n<p class=\"rtejustify\" style=\"text-align: justify;\">The contents of different water forms (\u041d<sub>2<\/sub>\u041e, \u041e\u041d-groups and others) in the quartz of a row of deposits had been fulfilled, using the methods of nuclei magnetic resonance (NMR) on <sup>1<\/sup>\u041d, <sup>23<\/sup>Na and <sup>27<\/sup>Al and X-ray diffraction. The quartz samples of different types from th\u0435 gold ore deposits of Muruntay , Allah-Yun and Onoch-Allah, Baley , Aksy , Berezivske, Dj-Katu, from deposits and ore manifestations of Ukraine (from the Krivoy Rog zone and from the different crossings of the Klinzi gold ore zone). Quartz samples from polymetallic ores (Sadon-Zgid, Chukotka), in that gold is practically absent, had been investigated additionally. The contents of water in inclusions (\u041d<sub>2<\/sub>\u041e<sub>inc<\/sub> molecules) and \u041e\u041d-groups in the quartz of different gold ore deposits were found by the <sup>1<\/sup>\u041d NMR method. The amount of the gas-liquid inclusions and their sizes in investigated samples differ substantially , what temperature dependences of \u041d<sub>2<\/sub>\u041e<sub>inc<\/sub> molecules content specify on. The practically linear dependence between intensities of the <sup>1<\/sup>\u041d NMR component caused by \u041e\u041d-groups and the <sup>27<\/sup>Al NMR component caused by AlIV in mica was established for the quartz samples, which <sup>1<\/sup>\u041d NMR spectra demonstrate two components \u2013 due to \u041d<sub>2<\/sub>\u041e<sub>inc<\/sub> molecules and \u041e\u041d-groups. This allowed to conclude the sericite type of \u041e\u041d- groups that is, these groups are contained in sericite. It is shown that <sup>23<\/sup>Na and <sup>27<\/sup>Al NMR data allow to establish the type of sericite impurities \u2013 muscovite-like or paragonite-like which content does not exceed the few parts percent. It is demonstrated that the quartz of gold ore deposits can be divided into three types, taking into account the content of different forms of water. The first type quartz has \u041d<sub>2<\/sub>\u041e<sub>inc<\/sub> molecules and \u041e\u041d- \u041e\u041d-groups of sericite type that specifies on the hydrothermal process\u00a0 following sericiting containing\u00a0 feldspars, quartz \u2013 sericite metasomatose. The second type quartz has \u041d<sub>2<\/sub>\u041e<sub>inc<\/sub> molecules mainly , in default or with the negligible amount of \u041e\u041d-groups of sericite type or other types that specifies on other type of the hydrothermal process. The content \u041d<sub>2<\/sub>\u041e<sub>inc<\/sub> molecules in the third type quartz does not exceed 0,01 wt% or they are absent, groups of sericite type or other type may be present or absent, that specifies on the insignificant hydrothermal process. It is established that the most of investigated quartz samples of gold ore deposits are the second type quartz, the less of the samples &#8211; the first type quartz and yet less than &#8211; the third type quartz. It is supposed, that metasomatose of the Klinzi gold ore deposit was similar to other deposits, but with considerably less intensity: the Baley-like quartz &#8211; sericite metasomatose was in near ore zone, the Muruntay-like metasomatose was in the ore zone. The data for quartz from cross quartz tendons of Muruntay deposit specify on a presence, on a less measure, two quartz generations. Quartz in the first generation is saturated by \u041d<sub>2<\/sub>\u041e<sub>inc<\/sub> molecules, water is absent in quartz of the second generation, that correlates with a well-known thesis about a multistage ore forming on this deposit. The formation temperatures of quartz from the deposits of Muruntay , Baley and Klinzi have been estimated on the basis of the NMR data. The obtained values correlate well with the well-known estimations of hydrotherm temperatures of these deposits and\u00a0 the temperatures of low tem- perature metasomatose (250-400 \u00b0\u0421).<\/p>\n<p class=\"rtejustify\" style=\"text-align: justify;\"><em>Key words: quartz, gold ore deposits, nuclei magnetic resonance, X-ray diffraction, hydrothermal processes.<\/em><\/p>\n<p>References<br \/>\n1. Voznyak, D.K. (2007). Mikrovklyuchennya ta rekonstruktsiya umov endohennoho mineraloutvorennya [Microinclusions and reconstruction of conditions of endogenous mineral forming]. Nauk. dumka, Kyiv . [In Ukrainian].<br \/>\n2. Deer, W.A.,Hovie, R.A. andZussman,J., (1962). Rock formingminerals.Vol. 4. Framework Silicates. Longmans, London.<br \/>\n3. Kalinichenko, O.A., Bryk, O.B., Kalinichenko, A.M., Bahmut, M.M., Yushyn, O.O. and Dudchenko, N.O. (2014), Zapysky Ukrayins\u2019koho mineralohichnoho tovarystva [Structural changes in feldspar rocks of Klyntsi gold ore by using nuclear magnetic resonance, Notes of Ukrainian Mineralogical Society], 14, pp. 47\u201357. [In Russian].<br \/>\n4. Kalyuzhnyy, V.A. (1982) Osnovy uchenyya o myneraloobrazuyushchykh flyuydakh [Fundamentals of mineral-forming fluids]. Nauk. dumka, Kyiv . [In Russian].<br \/>\n5. Snisar, V.P ., Kalinichenko, A.M., and Matyash, I.V. (1993). [A new view on the water source in the hydrothermal systems of the fault zones]. Reports of the Academy of Sciences of Ukraine. No. 1, P . 105\u2013108. [In Ukrainian].<br \/>\n6. Sushchevskaya, T .M, Kalynychenko, A.M., and Knyazeva, S.Y. (1989). [Analysis of water in inclusions in minerals using proton magnetic resonance (PMR)]. Geochemistry. 10, P . 1460\u20131465. [In Russian].<br \/>\n7. Fal\u2019kovych, A.L. (2005) [Geochemical features of gold mineralization (for example of Klyntsi gold ore manifestation)] Geological and Mineralogical Communications. No. 2, P . 105\u2013108. [In Russian].<br \/>\n8. Shyrokykh, Y.N. (1982), Trudy Instytuta Geolohyy y heofyzyky Sybyrskoho otdelenyya AN SSSR [Baley Wallrock metasomatic deposits in East Transbaikalia, In: Low-temperature hydrothermal mineralization and metasomatism, Proceedings of the Institute of Geology and Geophysics, Siberian Department of the Academy of Sciences of USSR], Nauka, Novosybyrsk, Vol. 505, P . 118\u2013142. [In Russian].<br \/>\n9. Kirkpatrick, R.J., Kinsey, R.A., Smith K.A., Henderson D.M., and Oldfield, E. (1985), High resolution solid-state sodium-23, aluminum-27, and silicon-29 nuclear magnetic resonance spectroscopic reconnaissance of alkali and plagioclase feldspars. Amer. Miner. 70, P . 106-123.<\/p>\n<p>&nbsp;<\/p>\n<p><a href=\"http:\/\/www.g-o-f.org.ua\/wp-content\/uploads\/2016\/7.pdf\">Download (PDF)<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Kalinichenko \u0415.\u0410., Brik \u0410.B., Kalinichenko \u0410.\u041c., Yushin A.A. M.P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation of the National Academy of Sciences of Ukraine Language: Ukrainian Geochemistry and ore formation 2016, 37: 65-73 https:\/\/doi.org\/10.15407\/gof.2016.37.065 The contents of different water forms (\u041d2\u041e, \u041e\u041d-groups and others) in the quartz of a row of deposits had been &hellip; <a href=\"http:\/\/www.g-o-f.org.ua\/gb\/archive\/2016-2\/%d0%b2%d0%b8%d0%bf%d1%83%d1%81%d0%ba-37\/%d0%b2%d0%be%d0%b4%d0%b0-%d0%b2-%d0%ba%d0%b2%d0%b0%d1%80%d1%86%d1%96-%d1%8f%d0%ba-%d1%96%d0%bd%d0%b4%d0%b8%d0%ba%d0%b0%d1%82%d0%be%d1%80-%d1%96%d0%bd%d1%82%d0%b5%d0%bd%d1%81%d0%b8%d0%b2%d0%bd%d0%be\/\" class=\"more-link\">Continue reading<span class=\"screen-reader-text\"> &#8220;Water in quartz as the indicator of intensity of hydrothermal ore formation: gold ore deposits&#8221;<\/span><\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"parent":227,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-701","page","type-page","status-publish","hentry"],"translation":{"provider":"WPGlobus","version":"3.0.0","language":"gb","enabled_languages":["uk","gb"],"languages":{"uk":{"title":true,"content":true,"excerpt":false},"gb":{"title":true,"content":true,"excerpt":false}}},"jetpack_sharing_enabled":true,"jetpack_shortlink":"https:\/\/wp.me\/P9ghyZ-bj","jetpack_likes_enabled":true,"jetpack-related-posts":[{"id":954,"url":"http:\/\/www.g-o-f.org.ua\/gb\/archive\/2018-39\/","url_meta":{"origin":701,"position":0},"title":"2018. Vol 39","author":"admin","date":"10\/12\/2018","format":false,"excerpt":"{:uk}\u0417\u041c\u0406\u0421\u0422 \u0417 \u043d\u0430\u0433\u043e\u0434\u0438 \u0441\u0442\u043e\u0440\u0456\u0447\u043d\u043e\u0433\u043e \u044e\u0432\u0456\u043b\u0435\u044e \u041d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u043e\u0457 \u0430\u043a\u0430\u0434\u0435\u043c\u0456\u0457 \u043d\u0430\u0443\u043a \u0423\u043a\u0440\u0430\u0457\u043d\u0438 \u041b.\u041c. \u0421\u0442\u0435\u043f\u0430\u043d\u044e\u043a, \u0421.\u0413. \u041a\u0440\u0438\u0432\u0434\u0456\u043a \u0413\u0435\u043e\u0445\u0456\u043c\u0456\u044f \u0442\u0430 \u0440\u0443\u0434\u043e\u0443\u0442\u0432\u043e\u0440\u0435\u043d\u043d\u044f 2018, 39: 3-5 \u0413\u0435\u043e\u0445\u0456\u043c\u0456\u044f \u0456 \u043f\u0435\u0442\u0440\u043e\u043b\u043e\u0433\u0456\u044f \u043f\u0440\u043e\u0446\u0435\u0441\u0456\u0432 \u043f\u043e\u0440\u043e\u0434\u043e- \u0442\u0430 \u0440\u0443\u0434\u043e\u0443\u0442\u0432\u043e\u0440\u0435\u043d\u043d\u044f \u0428\u0435\u0440\u0435\u043c\u0435\u0442 \u0415.\u041c., \u041d\u0438\u043a\u043e\u043b\u0430\u0435\u0432 \u0418.\u042e., \u0421\u0435\u0442\u0430\u044f \u041b.\u0414., \u0410\u0433\u0430\u0440\u043a\u043e\u0432\u0430 \u041d.\u0413. \u0412\u0438\u0434\u0456\u043b\u0435\u043d\u043d\u044f \u043f\u0440\u043e\u0433\u043d\u043e\u0437\u043d\u0438\u0445 \u043f\u043b\u043e\u0449 \u0437\u043e\u043d \u043c\u0435\u0442\u0430\u0441\u043e\u043c\u0430\u0442\u0438\u0442\u0456\u0432 \u0423\u043a\u0440\u0430\u0457\u043d\u0441\u044c\u043a\u043e\u0433\u043e \u0449\u0438\u0442\u0430 \u0433\u0435\u043e\u0435\u043b\u0435\u043a\u0442\u0440\u0438\u0447\u043d\u0438\u043c\u0438 \u043c\u0435\u0442\u043e\u0434\u0430\u043c\u0438 \u0413\u0435\u043e\u0445\u0456\u043c\u0456\u044f \u0442\u0430 \u0440\u0443\u0434\u043e\u0443\u0442\u0432\u043e\u0440\u0435\u043d\u043d\u044f 2018, 39: 6-15 https:\/\/doi.org\/10.15407\/gof.2018.39.006\u2026","rel":"","context":"Similar post","block_context":{"text":"Similar post","link":""},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":227,"url":"http:\/\/www.g-o-f.org.ua\/gb\/archive\/2016-2\/%d0%b2%d0%b8%d0%bf%d1%83%d1%81%d0%ba-37\/","url_meta":{"origin":701,"position":1},"title":"VOL 37.","author":"admin","date":"09\/10\/2017","format":false,"excerpt":"{:uk}\u0417\u041c\u0406\u0421\u0422 \u0413\u0435\u043e\u0445\u0456\u043c\u0456\u044f \u0456 \u043f\u0435\u0442\u0440\u043e\u043b\u043e\u0433\u0456\u044f \u043f\u0440\u043e\u0446\u0435\u0441\u0456\u0432 \u043f\u043e\u0440\u043e\u0434\u043e- \u0442\u0430 \u0440\u0443\u0434\u043e\u0443\u0442\u0432\u043e\u0440\u0435\u043d\u043d\u044f \u041a\u0440\u0438\u0432\u0434\u0456\u043a \u0421.\u0413., \u0428\u0430\u0440\u0438\u0433\u0456\u043d \u0412.\u0412., \u0413\u0430\u0446\u0435\u043d\u043a\u043e \u0412.\u041e., \u041b\u0443\u043d\u044c\u043e\u0432 \u0404.\u0421. \u0421\u043b\u044e\u0434\u0438 \u041f\u043e\u043a\u0440\u043e\u0432\u043e-\u041a\u0438\u0440\u0456\u0457\u0432\u0441\u044c\u043a\u043e\u0433\u043e \u043c\u0430\u0441\u0438\u0432\u0443 (\u041f\u0440\u0438\u0430\u0437\u043e\u0432\u2019\u044f, \u0423\u043a\u0440\u0430\u0457\u043d\u0430) \u0413\u0435\u043e\u0445\u0456\u043c\u0456\u044f \u0442\u0430 \u0440\u0443\u0434\u043e\u0443\u0442\u0432\u043e\u0440\u0435\u043d\u043d\u044f 2016, 37: 3-14 https:\/\/doi.org\/10.15407\/gof.2016.37.003 \u0417\u0430\u044f\u0446\u044c \u041e.\u0412., \u041b\u0430\u0440\u0456\u043a\u043e\u0432 \u0410.\u041b., \u0421\u043e\u0431\u043e\u043b\u0454\u0432 \u0412.\u0411., \u041a\u0443\u0448\u043d\u0456\u0440 \u0421.\u0412., \u0412\u0438\u0448\u043d\u0435\u0432\u0441\u044c\u043a\u0438\u0439 \u041e.\u0410., \u0421\u044c\u043e\u043c\u043a\u0430 \u041b.\u0412. \u0411\u0456\u043e\u0442\u0438\u0442\u0438 \u0440\u0456\u0434\u043a\u0456\u0441\u043d\u043e\u043c\u0435\u0442\u0430\u043b\u0435\u0432\u0438\u0445 \u0433\u0440\u0430\u043d\u0456\u0442\u0456\u0432 \u0420\u0443\u0441\u044c\u043a\u043e\u043f\u043e\u043b\u044f\u043d\u0441\u044c\u043a\u043e\u0433\u043e \u043c\u0430\u0441\u0438\u0432\u0443 (\u0406\u043d\u0433\u0443\u043b\u044c\u0441\u044c\u043a\u0438\u0439 \u043c\u0435\u0433\u0430\u0431\u043b\u043e\u043a \u0423\u0429) \u0413\u0435\u043e\u0445\u0456\u043c\u0456\u044f \u0442\u0430\u2026","rel":"","context":"Similar post","block_context":{"text":"Similar post","link":""},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":176,"url":"http:\/\/www.g-o-f.org.ua\/gb\/","url_meta":{"origin":701,"position":2},"title":"Geochemistry and ore formation","author":"admin","date":"09\/10\/2017","format":false,"excerpt":"{:uk}{:uk}\u0413\u0435\u043e\u0445\u0456\u043c\u0456\u044f \u0442\u0430 \u0440\u0443\u0434\u043e\u0443\u0442\u0432\u043e\u0440\u0435\u043d\u043d\u044f: \u0437\u0431. \u043d\u0430\u0443\u043a. \u043f\u0440. \/ \u041d\u0430\u0446. \u0430\u043a\u0430\u0434. \u043d\u0430\u0443\u043a \u0423\u043a\u0440\u0430\u0457\u043d\u0438, \u0406\u043d-\u0442 \u0433\u0435\u043e\u0445\u0456\u043c\u0456\u0457, \u043c\u0456\u043d\u0435\u0440\u0430\u043b\u043e\u0433\u0456\u0457 \u0442\u0430 \u0440\u0443\u0434\u043e\u0443\u0442\u0432\u043e\u0440\u0435\u043d\u043d\u044f \u0456\u043c. \u041c. \u041f. \u0421\u0435\u043c\u0435\u043d\u0435\u043d\u043a\u0430. \u2013 \u041a\u0438\u0457\u0432: [\u0431. \u0432.], 1972. - \u041f\u0435\u0440\u0456\u043e\u0434\u0438\u0447\u043d\u0456\u0441\u0442\u044c: \u0434\u043e \u0434\u0432\u043e\u0445 \u0440\u0430\u0437\u0456\u0432 \u043d\u0430 \u0440\u0456\u043a. ISSN 2224-6487 (print) ISSN 2617-3395 (online) \u0422\u0435\u043c\u0430\u0442\u0438\u043a\u0430: \u0434\u0440\u0443\u043a\u0443\u044e\u0442\u044c\u0441\u044f \u043e\u0440\u0438\u0433\u0456\u043d\u0430\u043b\u044c\u043d\u0456 \u0441\u0442\u0430\u0442\u0442\u0456, \u043e\u0433\u043b\u044f\u0434\u0438, \u0440\u0435\u0446\u0435\u043d\u0437\u0456\u0457 \u0442\u0430 \u043c\u0430\u0442\u0435\u0440\u0456\u0430\u043b\u0438 \u0445\u0440\u043e\u043d\u0456\u043a\u0430\u043b\u044c\u043d\u043e\u0433\u043e \u0445\u0430\u0440\u0430\u043a\u0442\u0435\u0440\u0443, \u0449\u043e \u0432\u0438\u0441\u0432\u0456\u0442\u043b\u044e\u044e\u0442\u044c\u2026","rel":"","context":"In \"\u0413\u0435\u043e\u0445\u0456\u043c\u0456\u044f \u0442\u0430 \u0440\u0443\u0434\u043e\u0443\u0442\u0432\u043e\u0440\u0435\u043d\u043d\u044f\"","block_context":{"text":"\u0413\u0435\u043e\u0445\u0456\u043c\u0456\u044f \u0442\u0430 \u0440\u0443\u0434\u043e\u0443\u0442\u0432\u043e\u0440\u0435\u043d\u043d\u044f","link":"http:\/\/www.g-o-f.org.ua\/gb\/tag\/%d0%b3%d0%b5%d0%be%d1%85%d1%96%d0%bc%d1%96%d1%8f-%d1%82%d0%b0-%d1%80%d1%83%d0%b4%d0%be%d1%83%d1%82%d0%b2%d0%be%d1%80%d0%b5%d0%bd%d0%bd%d1%8f\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":1510,"url":"http:\/\/www.g-o-f.org.ua\/gb\/archive\/2019-40\/1-2\/","url_meta":{"origin":701,"position":3},"title":"The Institute of Geochemistry, Mineralogy and Ore Formation Semenenko NAS of Ukraine is 50 years","author":"admin","date":"27\/11\/2019","format":false,"excerpt":"{:uk}9 \u0441\u0456\u0447\u043d\u044f 2019 \u0440. \u0406\u043d\u0441\u0442\u0438\u0442\u0443\u0442\u0443 \u0433\u0435\u043e\u0445\u0456\u043c\u0456\u0457, \u043c\u0456\u043d\u0435\u0440\u0430\u043b\u043e\u0433\u0456\u0457 \u0442\u0430 \u0440\u0443\u0434\u043e\u0443\u0442\u0432\u043e\u0440\u0435\u043d\u043d\u044f \u0456\u043c. \u041c.\u041f. 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post","link":""},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":870,"url":"http:\/\/www.g-o-f.org.ua\/gb\/%d0%bd%d0%be%d0%b2%d0%b8%d0%bd%d0%b8\/","url_meta":{"origin":701,"position":5},"title":"News","author":"admin","date":"29\/10\/2018","format":false,"excerpt":"{:uk} 10.02.2022 \u0428\u0430\u043d\u043e\u0432\u043d\u0456 \u043a\u043e\u043b\u0435\u0433\u0438!!! \u041f\u043e\u0432\u0456\u0434\u043e\u043c\u043b\u044f\u0454\u043c\u043e \u0412\u0430\u043c, \u0449\u043e \u0440\u043e\u0437\u043f\u043e\u0447\u0430\u0442\u0430 \u043f\u0456\u0434\u0433\u043e\u0442\u043e\u0432\u043a\u0430 \u0434\u043e \u0434\u0440\u0443\u043a\u0443 \u0447\u0435\u0440\u0433\u043e\u0432\u043e\u0433\u043e \u0432\u0438\u043f\u0443\u0441\u043a\u0443 \u0437\u0431\u0456\u0440\u043d\u0438\u043a\u0430 \u00ab\u0413\u0435\u043e\u0445\u0456\u043c\u0456\u044f \u0442\u0430 \u0440\u0443\u0434\u043e\u0443\u0442\u0432\u043e\u0440\u0435\u043d\u043d\u044f\u00bb. \u0427\u0435\u043a\u0430\u0454\u043c\u043e 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