{"id":2303,"date":"2024-12-18T19:08:53","date_gmt":"2024-12-18T17:08:53","guid":{"rendered":"http:\/\/www.g-o-f.org.ua\/?page_id=2303"},"modified":"2024-12-18T19:08:53","modified_gmt":"2024-12-18T17:08:53","slug":"gof-2024-45-021","status":"publish","type":"page","link":"http:\/\/www.g-o-f.org.ua\/gb\/archive\/2024-45\/gof-2024-45-021\/","title":{"rendered":"MELANOCRATIC ROCK OF THE SYENITE-TVAITOSITE SERIES OF THE CHERNIHIVKA CARBONATITE MASSIF (AZOV REGION)"},"content":{"rendered":"<p><strong>O.V. Dubyna <\/strong><sup><strong>1, 2<\/strong><br \/>\n<\/sup><a href=\"https:\/\/orcid.org\/0000-0002-6003-4873\">https:\/\/orcid.org\/0000-0002-6003-4873<\/a><\/p>\n<p><strong>S.G. Kryvdik <\/strong><sup><strong>1<\/strong><br \/>\n<\/sup><a href=\"https:\/\/orcid.org\/0000-0002-8356-1115\">https:\/\/orcid.org\/0000-0002-8356-1115<\/a><\/p>\n<p><strong>O.A. Vyshnevskyi <\/strong><sup><strong>1<\/strong><br \/>\n<\/sup><a href=\"https:\/\/orcid.org\/0000-0002-7206-2185\">https:\/\/orcid.org\/0000-0002-7206-2185<\/a><\/p>\n<p><sup>1<\/sup> M.P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation of the NAS of Ukraine 34, Acad. Palladin Ave., Kyiv, Ukraine, 03142<br \/>\n<sup>2<\/sup> Taras Shevchenko National University of Kyiv, Institute of Geology 90, Vasylkivska Str., Kyiv, Ukraine, 03022<\/p>\n<p><a href=\"https:\/\/doi.org\/10.15407\/gof.2024.45.021\">https:\/\/doi.org\/10.15407\/gof.2024.45.021<\/a><\/p>\n<p style=\"text-align: justify;\">The results of mineralogical studies of melanocratic apatite-enriched albite-pyroxene rocks of the Chernihivka carbonatite massif are presented. The studied rock was discovered by drilling among alkaline syenites. This rock is represented by vein- like body (thickness up to 30-50 cm). The rock-forming minerals are aegirine-diopside, albite, ferruginous phlogopite, amphibole (edenite-katophorite series) and apatite (up to 20%); accessory \u2014 calcite, allanite and pyrite. The studied rock is similar by mineral composition and high apatite content to tvaitosites and tvaitosite-pyroxenites of the massif, which are more distributed in the northern and central parts. However, it differs from them in the composition of phlogopite and amphibole. The latter is not characteristic for typical tvaitosites and tvaitosite-pyroxenites. The obtained preliminary data make it possible to put forward only hypothetical considerations regarding the genesis of this rock. Quit possible their origin could be related with separation of alkaline essentially aqueous fluids from the primary carbonatite melt with subsequent migration into hosted alkaline syenites. The subsequent reaction of these fluids with hosted rocks could lead to the recrystallization of initial feldspar to albite and appearance of secondary calcite, phlogopite, amphibole, and apatite. At the same time, it is assumed that tvaitosites &#8211; tvaitosite-pyroxenites series were formed as result of syenite melt differentiations (pyroxene fractionation), since they are composed of the same minerals as the hosted alkaline syenites and main difference between these rocks is only in proportion of pyroxene.<\/p>\n<p><strong><em>Key words: <\/em><\/strong><em>tvaitosite, aegirine-diopside, edenite-katophorite amphibole, carbonatites.<\/em><\/p>\n<p><a href=\"http:\/\/www.g-o-f.org.ua\/wp-content\/uploads\/2024\/12\/gof.2024.45.021.pdf\" target=\"_blank\" rel=\"noopener\">Download (PDF)<\/a><\/p>\n<p>References:<\/p>\n<p>1. Hlevasskiy, E.B., Kryvdik, S.G. (1981). Precambrian carbonatite complex of the Azov region. Nauk. Dumka, Kyiv. 227 p. [in Russian].<br \/>\n2. Dubyna, O.V. (2008). Petrochemical features and chemical formation of meadow rocks of the Proskurivka massif (Bug area). Geochemistry and Ore Formation, 26. p. 46-57 [in Ukrainian].<br \/>\n3. Zhukov, G.V., Varkhotov, V.A., Sakhatsky, I.I., Goryaev, Yu.P. (1973). On the discovery of phosphate mineralization in Zapadnyam Priazovye. Geol. Journ., 33, No. 5. p. 150-152 [in Russian].<br \/>\n4. Zagnitko, V.N., Lugovaya, I.P. (1989). Isotope geochemistry of carbonate and ferruginous-siliceous rocks of the Ukrainian Shield. Nauk. Dumka, Kyiv. 316 p. [in Russian].<br \/>\n5. Kravchenko, G.L., Kryvdik, S.G., Rusakov, N.F. (2008). Features of the Begim-Chokrak occurrence of alkaline ultrabasic rocks and carbonatites (Western Azov region). Geochemistry and Ore Formation, 26. p. 21-45 [in Russian]. 6. Kryvdik, S.H. (2017). Apofenite albitites of the Ukrainian Shield. Geochemistry and Ore Formation, 38. p. 58-69 [in Ukrainian].<br \/>\n7. Kryvdik, S.G., Zagnitko, V.N., Lugovaya, I.P. (1997). Isotopic composition of minerals in carbonatites of the Chernigovka massif as an indicator of their crystallization conditions. Mineral. Journ. (Ukraine). No. 6. p. 28-42 [in Russian].<br \/>\n8. Kryvdik, S.G., Tkachuk, V.I. (1990). Petrology of alkaline rocks of the Ukrainian Shield. Nauk. Dumka, Kyiv. 408 p. [in Russian].<br \/>\n9. Novopoltavskoye(Chernigovskoye) carbonatiteapatite-raremetaldepositofthe Ukrainian Shield. Ed. A.N. Ponomarenko. Kharkov: FLP Mezina V.V., 2019 [in Russian].<br \/>\n10. Shramenko, I.F., Stadnik, V.A., Osadchiy, V.K. (1992). Geochemistry of carbonatites of the Ukrainian shield. Nauk. Dumka, Kyiv. 212 p. [in Russian].<br \/>\n11. Druppel K.D., Hoefs J., Okruch M. (2005). Fenitizing Processes Induced by Ferrocarbonatite Magmatism at Swartbooisdrif, NW Namibia. Journ. of Petrol. 46, No. 2. P. 377-406. https:\/\/doi.org\/10.1093\/petrology\/egh081<br \/>\n12. Le Bas, M.J., (1977). Carbonatite-Nephelinite Volcanism. Wiley &amp; Sons, London. 347p.<br \/>\n13. Le Bas, M.J. (2008). Fenites Associated with Carbonatites. The Canadian Mineralogist, 46, P. 915-932. https:\/\/doi.org\/10.3749\/canmin.46.4.915<br \/>\n14. Vartiainen, Heikki, Wooley, Alan R. (1976). The petrography, mineralogy and chemistry of the fenites of the Sokli carbonatite intrusion, Finland. Bulletin de la Commission G\u00e9ologique de Finlande. 280.<br \/>\n15. Woolley, A.R. (1982). A discussion of carbonatite evolution and nomenclature, and the generation of sodic and potassic fenites. Mineral. Mag. 46. P. 13-17. https:\/\/doi.org\/10.1180\/minmag.1982.046.338.03<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>O.V. Dubyna 1, 2 https:\/\/orcid.org\/0000-0002-6003-4873 S.G. Kryvdik 1 https:\/\/orcid.org\/0000-0002-8356-1115 O.A. Vyshnevskyi 1 https:\/\/orcid.org\/0000-0002-7206-2185 1 M.P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation of the NAS of Ukraine 34, Acad. Palladin Ave., Kyiv, Ukraine, 03142 2 Taras Shevchenko National University of Kyiv, Institute of Geology 90, Vasylkivska Str., Kyiv, Ukraine, 03022 https:\/\/doi.org\/10.15407\/gof.2024.45.021 The results of &hellip; <a href=\"http:\/\/www.g-o-f.org.ua\/gb\/archive\/2024-45\/gof-2024-45-021\/\" class=\"more-link\">Continue reading<span class=\"screen-reader-text\"> &#8220;MELANOCRATIC ROCK OF THE SYENITE-TVAITOSITE SERIES OF THE CHERNIHIVKA CARBONATITE MASSIF (AZOV REGION)&#8221;<\/span><\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"parent":2268,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-2303","page","type-page","status-publish","hentry"],"translation":{"provider":"WPGlobus","version":"3.0.0","language":"gb","enabled_languages":["uk","gb"],"languages":{"uk":{"title":true,"content":true,"excerpt":false},"gb":{"title":true,"content":true,"excerpt":false}}},"jetpack_sharing_enabled":true,"jetpack_shortlink":"https:\/\/wp.me\/P9ghyZ-B9","jetpack_likes_enabled":true,"jetpack-related-posts":[{"id":2345,"url":"http:\/\/www.g-o-f.org.ua\/gb\/archive\/2024-45\/gof-2024-45-064\/","url_meta":{"origin":2303,"position":0},"title":"URANIUM MINERALIZATION IN ROCKS OF THE PETRIVSK IRON ORE DEPOSIT (INGUL MEGABLOCK, UKRAINIAN SHIELD)","author":"admin","date":"18\/12\/2024","format":false,"excerpt":"{:uk}\u041e.\u0412. \u041a\u043e\u0432\u0442\u0443\u043d kovtun85@ukr.net; https\/\/orcid: 0000-0003-0475-8778 \u041b.\u041c. \u0421\u0442\u0435\u043f\u0430\u043d\u044e\u043a stepaniuk@nas.gov.ua, https:\/\/orcid.org\/0000-0001-5591-5169 \u041e.\u0412. \u0417\u044e\u043b\u044c\u0446\u043b\u0435 olegzjults@gmail.com, https:\/\/orcid.org\/0000-0002-6204-2009 \u041e.\u0411. \u0412\u0438\u0441\u043e\u0446\u044c\u043a\u0438\u0439 alek.vysotsky@gmail.com; https\/\/orcid.org\/0000-0002-3542-4685 \u0422.\u0406. \u0414\u043e\u0432\u0431\u0443\u0448 tetyana.dovbush1@gmail.com, https:\/\/orcid.org\/0000-0002-3512-3313 \u0413.\u0413. \u041f\u0430\u0432\u043b\u043e\u0432 genychpavlov@gmail.com; https\/\/orcid.org\/0000-0002-5913-042X \u041d.\u041e. \u041a\u043e\u0432\u0430\u043b\u0435\u043d\u043a\u043e https:\/\/orcid.org\/0000-0002-3203-7145 \u0406\u043d\u0441\u0442\u0438\u0442\u0443\u0442 \u0433\u0435\u043e\u0445\u0456\u043c\u0456\u0457, \u043c\u0456\u043d\u0435\u0440\u0430\u043b\u043e\u0433\u0456\u0457 \u0442\u0430 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\u043c\u0456\u043d\u0435\u0440\u0430\u043b\u043e\u0433\u0456\u0457 \u0442\u0430 \u0440\u0443\u0434\u043e\u0443\u0442\u0432\u043e\u0440\u0435\u043d\u043d\u044f \u0456\u043c. \u041c.\u041f. \u0421\u0435\u043c\u0435\u043d\u0435\u043d\u043a\u0430 \u041d\u0410\u041d \u0423\u043a\u0440\u0430\u0457\u043d\u0438 \u043f\u0440\u043e\u0441\u043f. \u0430\u043a\u0430\u0434. \u041f\u0430\u043b\u043b\u0430\u0434\u0456\u043d\u0430, 34, \u041a\u0438\u0457\u0432, \u0423\u043a\u0440\u0430\u0457\u043d\u0430, 03142 https:\/\/doi.org\/10.15407\/gof.2024.45.044 \u0412\u0438\u043a\u043b\u0430\u0434\u0435\u043d\u043e \u0440\u0435\u0437\u0443\u043b\u044c\u0442\u0430\u0442\u0438 \u0432\u0438\u0432\u0447\u0435\u043d\u043d\u044f \u0433\u0440\u0430\u043d\u0456\u0442\u0443 \u043d\u0435\u0440\u0456\u0432\u043d\u043e\u043c\u0456\u0440\u043d\u043e\u0437\u0435\u0440\u043d\u0438\u0441\u0442\u043e\u0433\u043e (\u043f\u0440\u043e\u0431\u0430 14\/23), \u043f\u0435\u0433\u043c\u0430\u0442\u043e\u0457\u0434\u043d\u043e\u0433\u043e \u0433\u0440\u0430\u043d\u0456\u0442\u0443\u2026","rel":"","context":"Similar post","block_context":{"text":"Similar post","link":""},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":2425,"url":"http:\/\/www.g-o-f.org.ua\/gb\/archive\/2025-46\/gof-2025-46-056\/","url_meta":{"origin":2303,"position":2},"title":"AGE OF METAVOLCANIC ROCKS OF ACIDIC COMPOSITION OF THE METAMORPHIC COMPLEX OF THE NORTHWESTERN PART OF THE MARMAROSH MASSIF (UKRAINIAN CARPATHIANS)","author":"admin","date":"16\/12\/2025","format":false,"excerpt":"{:uk}\u041b.\u041c. \u0421\u0442\u0435\u043f\u0430\u043d\u044e\u043a, stepaniuk@nas.gov.ua, https:\/\/orcid.org\/0000-0001-5591-5169\u00a0 \u0422.\u0406. \u0414\u043e\u0432\u0431\u0443\u0448, tetyana.dovbush1@gmail.com, https:\/\/orcid.org\/0000-0002-3512-3313 \u041e.\u0411.\u00a0 \u00a0\u0412\u0438\u0441\u043e\u0446\u044c\u043a\u0438\u0439,\u00a0 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MASSIF AND ITS FRAMING (INGUL MEGABLOCK OF THE UKRAINIAN SHIELD)","author":"admin","date":"15\/12\/2021","format":false,"excerpt":"{:uk}\u041b.\u041c. \u0421\u0442\u0435\u043f\u0430\u043d\u044e\u043a 1https:\/\/orcid.org\/0000-0001-5591-5169E-mail: stepaniuk@nas.gov.ua\u0421.\u0406. \u041a\u0443\u0440\u0438\u043b\u043e 2E-mail: kurylo.sergiy@gmail.com;https:\/\/orcid.org\/0000-0003-4466-6851\u0412.\u041e. \u0421\u044c\u043e\u043c\u043a\u0430 1E-mail: syomka1949@gmail.com;https:\/\/orcid.org\/0000-0001-5202-4045\u0422.\u0406. \u0414\u043e\u0432\u0431\u0443\u0448 1https:\/\/orcid.org\/0000-0002-3512-3313E-mail: tetyana.dovbush1@gmail.com\u0421.\u041c. \u0411\u043e\u043d\u0434\u0430\u0440\u0435\u043d\u043a\u043e 1E-mail: sbond.igmr@gmail.com;\u00a0https:\/\/orcid.org\/0000-0001-7948-3583\u041e.\u0412. \u041a\u043e\u0432\u0442\u0443\u043d 1, 3E-mail: kovtun85@ukr.net;https:\/\/orcid.org\/0000-0003-0475-8778\u0406.\u041c. \u041a\u043e\u0442\u0432\u0456\u0446\u044c\u043a\u0430 1E-mail: irinakotvitska@gmail.com1. \u0406\u043d\u0441\u0442\u0438\u0442\u0443\u0442 \u0433\u0435\u043e\u0445\u0456\u043c\u0456\u0457, \u043c\u0456\u043d\u0435\u0440\u0430\u043b\u043e\u0433\u0456\u0457 \u0442\u0430 \u0440\u0443\u0434\u043e\u0443\u0442\u0432\u043e\u0440\u0435\u043d\u043d\u044f \u0456\u043c\u0435\u043d\u0456 \u041c.\u041f. \u0421\u0435\u043c\u0435\u043d\u0435\u043d\u043a\u0430 \u041d\u0410\u041d \u0423\u043a\u0440\u0430\u0457\u043d\u043803142, \u043f\u0440\u043e\u0441\u043f. \u0430\u043a\u0430\u0434. \u041f\u0430\u043b\u043b\u0430\u0434\u0456\u043d\u0430, 34, \u041a\u0438\u0457\u0432, \u0423\u043a\u0440\u0430\u0457\u043d\u04302. \u0406\u043d\u0441\u0442\u0438\u0442\u0443\u0442 \u043d\u0430\u0443\u043a \u043f\u0440\u043e \u0417\u0435\u043c\u043b\u044e \u0421\u043b\u043e\u0432\u0430\u0446\u044c\u043a\u0430 \u0430\u043a\u0430\u0434\u0435\u043c\u0456\u044f \u043d\u0430\u0443\u043a97401, \u0414\u0443\u043c\u0431\u0456\u0454\u0440\u0441\u044c\u043a\u0430, 1, \u0411\u0430\u043d\u0441\u044c\u043a\u0430-\u0411\u0438\u0441\u0442\u0440\u0438\u0446\u044f, \u0421\u043b\u043e\u0432\u0430\u0447\u0447\u0438\u043d\u04303.\u2026","rel":"","context":"Similar post","block_context":{"text":"Similar post","link":""},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":1774,"url":"http:\/\/www.g-o-f.org.ua\/gb\/archive\/2020-41\/7-2\/","url_meta":{"origin":2303,"position":4},"title":"Uranium-lead age of granites Chigirin massif","author":"admin","date":"09\/12\/2020","format":false,"excerpt":"{:uk}\u041b.\u041c. \u0421\u0442\u0435\u043f\u0430\u043d\u044e\u043a 1 https:\/\/orcid.org\/0000-0001-5591-5169 \u041d.\u041c. \u041a\u043e\u043d\u043e\u0432\u0430\u043b 1 E-mail: nasa246@ukr.net, https:\/\/orcid.org\/orcid.org\/0000-0002-5645-0110 \u041e.\u0411. \u0412\u0438\u0441\u043e\u0446\u044c\u043a\u0438\u0439 1 https:\/\/orcid.org\/0000-0002-3542-4685 \u0422.\u0406. \u0414\u043e\u0432\u0431\u0443\u0448 1 https:\/\/orcid.org\/0000-0002-3512-3313 \u041e.\u0412. \u0411\u0456\u043b\u0430\u043d 2 https:\/\/orcid.org\/0000-0003-0964-6003 1 \u0406\u043d\u0441\u0442\u0438\u0442\u0443\u0442 \u0433\u0435\u043e\u0445\u0456\u043c\u0456\u0457, \u043c\u0456\u043d\u0435\u0440\u0430\u043b\u043e\u0433\u0456\u0457 \u0442\u0430 \u0440\u0443\u0434\u043e\u0443\u0442\u0432\u043e\u0440\u0435\u043d\u043d\u044f \u0456\u043c\u0435\u043d\u0456 \u041c.\u041f. \u0421\u0435\u043c\u0435\u043d\u0435\u043d\u043a\u0430 \u041d\u0410\u041d \u0423\u043a\u0440\u0430\u0457\u043d\u0438, 03142, \u043f\u0440\u043e\u0441\u043f. \u0430\u043a\u0430\u0434. \u041f\u0430\u043b\u043b\u0430\u0434\u0456\u043d\u0430, 34, \u041a\u0438\u0457\u0432, \u0423\u043a\u0440\u0430\u0457\u043d\u0430 2 \u041a\u0438\u0457\u0432\u0441\u044c\u043a\u0438\u0439 \u043d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442 \u0456\u043c\u0435\u043d\u0456 \u0422\u0430\u0440\u0430\u0441\u0430 \u0428\u0435\u0432\u0447\u0435\u043d\u043a\u0430, \u041d\u0430\u0432\u0447\u0430\u043b\u044c\u043d\u043e-\u043d\u0430\u0443\u043a\u043e\u0432\u0438\u0439 \u0456\u043d\u0441\u0442\u0438\u0442\u0443\u0442 \u00ab\u0406\u043d\u0441\u0442\u0438\u0442\u0443\u0442\u2026","rel":"","context":"Similar post","block_context":{"text":"Similar post","link":""},"img":{"alt_text":"","src":"https:\/\/i0.wp.com\/www.g-o-f.org.ua\/wp-content\/uploads\/2020\/index.jpg?resize=350%2C200","width":350,"height":200},"classes":[]},{"id":2124,"url":"http:\/\/www.g-o-f.org.ua\/gb\/archive\/2023-44\/4-4\/","url_meta":{"origin":2303,"position":5},"title":"GEOCHEMISTRY OF FLUORINE OF SEDIMENTARY ROCKS OF DIFFERENT MASSES OF THE CARPATIAN BIOSPHERE RESERVE","author":"admin","date":"17\/12\/2023","format":false,"excerpt":"{:uk}{:uk}{:uk}{:uk} {:uk}\u041d.\u041e. \u041a\u0440\u044e\u0447\u0435\u043d\u043a\u043e 1 E-mail: nataliya.kryuchenko@gmail.com, https:\/\/orcid.org\/0000-0001-8774-90 \u0415 \u042f. \u0416\u043e\u0432\u0438\u043d\u0441\u044c\u043a\u0438\u0439 1 E-mail: zhovinsky@ukr.net, https:\/\/orcid.org\/0000-0003-1601-5998 \u041f.\u0421. \u041f\u0430\u043f\u0430\u0440\u0438\u0433\u0430 2 E-mail: paparyga.ps@ukr.net, https:\/\/orcid.org\/0000-0002-4021-0809 \u041e.\u0410. \u0416\u0443\u043a 1 E-mail: igmof.zhuk@gmail.com, https:\/\/orcid.org\/ 0000-0002-5264-0750 \u041c.\u0412. \u041a\u0443\u0445\u0430\u0440 1 E-mail: mvk2819@gmail.com, https:\/\/orcid.org\/0000-0003-3572-5194 1 \u0406\u043d\u0441\u0442\u0438\u0442\u0443\u0442 \u0433\u0435\u043e\u0445\u0456\u043c\u0456\u0457, \u043c\u0456\u043d\u0435\u0440\u0430\u043b\u043e\u0433\u0456\u0457 \u0442\u0430 \u0440\u0443\u0434\u043e\u0443\u0442\u0432\u043e\u0440\u0435\u043d\u043d\u044f \u0456\u043c\u0435\u043d\u0456 \u041c.\u041f. \u0421\u0435\u043c\u0435\u043d\u0435\u043d\u043a\u0430 \u041d\u0410\u041d \u0423\u043a\u0440\u0430\u0457\u043d\u0438 03142, \u043f\u0440\u043e\u0441\u043f. \u0410\u043a\u0430\u0434. \u041f\u0430\u043b\u043b\u0430\u0434\u0456\u043d\u0430, 34, \u041a\u0438\u0457\u0432,\u2026","rel":"","context":"Similar post","block_context":{"text":"Similar 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